N,N,N′,N′-Tetra­methyl­ethylene­diammonium tetra­chloridocobaltate(II)

نویسندگان

  • Russell G. Baughman
  • Rebecca S. Shane
  • James M. McCormick
چکیده

The asymmetric unit of the title compound, [(CH(3))(2)NH(CH(2))(2)NH(CH(3))(2)][CoCl(4)], contains a tetra-chlorido-cobalt-ate(II) dianion and two halves of two centrosymmetric, crystallographically-independent, dications. One independent dication is disordered between two conformations in a 0.784 (13):0.216 (13) ratio. In the crystal, inter-molecular N-H⋯Cl hydrogen bonds link cations and anions into chains propagated in [01]. These hydrogen bonds contribute to the distorted tetra-hedral geometry at the Co(II) atom.

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عنوان ژورنال:

دوره 67  شماره 

صفحات  -

تاریخ انتشار 2010